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Science Quickly

Knot Not Easy to Knot

Science Quickly

Scientific American

Science

4.41.4K Ratings

🗓️ 18 January 2017

⏱️ 2 minutes

🧾️ Download transcript

Summary

Chemists have synthesized the most complex molecular knot ever, using a strand just 192 atoms long. The advance could lead to new tougher materials. Christopher Intagliata reports. Learn more about your ad choices. Visit megaphone.fm/adchoices

Transcript

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0:00.0

This is them is new ways to tie knots. There are more than 6 billion different types of knots that have been

0:16.4

tabulated by mathematicians, 6 billion.

0:19.4

David Lee, a chemist at the University of Manchester in the UK.

0:23.0

The hard party says is actually making them.

0:25.0

Just because I can see a knitted jumper

0:28.0

doesn't mean that I can actually make one.

0:30.0

Because what Lee and his colleagues are interested in

0:32.0

is tying molecular knots,

0:34.3

using strands that are 10,000 times thinner than a human hair.

0:38.4

With a molecule, you can't just grab hold of the ends and tie them like you with a shoelace. They're too small for that and

0:46.0

instead you've got to use chemistry to make the molecules sort of fold themselves round

0:52.4

into the precise way that you need to form the

0:56.7

particular knot. Continuing the shoelace analogy, remember when you were learning to

1:01.3

tie your shoes, your mom or dad put a finger in the middle of the nut to make it easier to tie?

1:06.0

Well, Lee and his team did something similar, but they used metal ions as the fingers to keep the knot tying organized. Then tiny molecular strands,

1:14.8

just 192 atoms long, assembled themselves around the ions. And then mom pulls a

1:22.0

finger out and we extract the metal lines out and you're left just with the

1:26.2

knot at the end.

1:27.2

The most complex molecular knot ever synthesized, the studies in the journal Science. Now knots were hugely useful to our ancestors in the stone age.

1:37.0

Fishing nets and axes with blades tied to the handles and how to weave fabrics to keep him warm.

1:43.7

And Lee says knots could be just as helpful in the molecular world,

1:47.8

like for stronger braided polymers,

...

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