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Discovery

Phosphorus

Discovery

BBC

Science, Technology

4.31.2K Ratings

🗓️ 5 March 2018

⏱️ 27 minutes

🧾️ Download transcript

Summary

What links trade unions with urine, Syria with semiconductors, and bones and bombs? The answer is phosphorus, UCL Inorganic Chemistry Professor Andrea Sella, who is himself engaged in researching new phosphorus based materials, looks at this often rather frightening element. We hear how the health impact of phosphorus on a group of Irish girls changed politics, how the element has been used as a weapon of war and we peer into the future, as chemists break new ground on what might be possible with phosphorus and nanotechnology.

Photo: BBC Copyright

Transcript

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0:00.0

Just before this BBC podcast gets underway, here's something you may not know.

0:04.7

My name's Linda Davies and I Commission Podcasts for BBC Sounds.

0:08.5

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0:24.6

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0:29.7

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0:36.0

This is the BBC.

0:41.0

So this is just to purify some manky white phosphorus to get a nice element that we know is

0:49.0

100% phosphorus which we can then use to fill the nanotude with.

0:53.0

In a lab at UCL, postgraduate student Martin Hart is gently warming some phosphorus in a flask under vacuum.

1:00.0

We can heat the old stuff and then condensing it onto a cold finger.

1:05.2

This gives us a lovely covered cold finger of incredibly pure white phosphorus.

1:10.6

So this liquid nitrogen which we use to cool down the finger and allow the

1:15.8

sublimation of the phosphorus onto the probe. The phosphorus sublims, it vaporizes, and then sticks to a gloss surface, the cold finger,

1:26.4

that is cooled with liquid nitrogen. What he's talking about is purifying one of the most dangerously

1:32.4

flammable materials ever discovered,

1:35.0

white phosphorus.

1:37.0

So we can just kick this along a little bit of heat.

1:41.0

The result is a white solid that will ignite instantaneously if it meets air.

1:47.0

This is chemistry at its most extreme, the chemistry of one of the strangest elements in the periodic table. I am Andrea Sahela, Professor. of This is my lab and I want to tell you about phosphorus and the extraordinary contributions it has made to our lives, to our wars and to our politics.

2:10.0

You can start to see it very faintly starting to supply them from the walls of the vessel onto the

2:19.6

probe which is being caused by the liquor nitrous.

...

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